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Trail pheromone of the Pharaoh's ant, monomorium pharaonis: isolation and identification of faranal, a terpenoid related to juvenile hormone II

✍ Scribed by F.J. Ritter; I.E.M. Brüggemann-Rotgans; P.E.J. Verwiel; C.J. Persoons; E. Talman

Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 128 KB
Volume: 18
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)83835-1

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✦ Synopsis

The poison gland of the Pharaoh's ant contains two attractive alcaloidal pheromones, which are components of its odour trail l-3 . The Dufour's gland, however, produces trace amounts of a much more active compound, the true trail pheromone. We now wish to describe

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## Abstract Faranal (1), the trail‐following pheromone of the worker of Pharaoh's ant (__Monomorium pharaonis__), was synthesized by the coupling reaction of the iododiene 3 with the chiral building block 8 as the key step. The geometrically pure iododiene 3 was prepared by the zirconocene‐mediated