The tracer diffusion coefficients of the Cu and Cl species, in molten CuCl between 450°C and 75O"C, were measured using a capillary technique. The experiments revealed an unusually large difference between the cationic and anionic diffusion coefficients. The results were discussed in terms of the m
Tracer diffusion coefficients in molten salts—I. Methods
✍ Scribed by K. Grjotheim; T. Naterstad; K.E. Torklep; H.A. Øye
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 540 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
Two different methods for determination of tracer dilfusion coefficients in molten salts are presented. Both methods were based on the theory related to diffusion of instantaneously applied. infinitely thin radioactive sources in semi-infinite one-dimensional diffusion media.
In the first method, the melt was absorbed in sintered. porous MgO-strips. The labyrinth factors for these "Impregnated Self-supporting Strips" (1%) were known from calibration measurements.
The second method used was a direct method. In this case the melt was kept as a "Cylindrical Thin Layer" (CTL) of thickness 0.025JJ.030 cm in a graphite crucible facilitating effective quenching of the melt after the experiment.
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