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Towards polyketide libraries: Iterative, asymmetric aldol reactions on a solid support

✍ Scribed by Michael Reggelin; Volker Brenig

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
142 KB
Volume
37
Category
Article
ISSN
0040-4039

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A new fluoride ion cleavable linker serves as starter unit for iterative asymmetric aldol reactions on a solid support. The synthetic protocol relies on the boron enolate chemistry of D. A. Evans and a cyclic reestablishment of key functionalities. It entails the opportunity for the generation ofdi-