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Towards a total synthesis of ulapualide A. Concise synthetic routes to the tris-oxazole ring system and tris-oxazole macrolide core in ulapualides, kabiramides, halichondramides, mycalolides and halishigamides

✍ Scribed by Chattopadhyay, Shital K.; Kempson, James; McNeil, Alan; Pattenden, Gerald; Reader, Michael; Rippon, David E.; Waite, David

Book ID: 118001407
Publisher: Royal Society of Chemistry
Year: 2000
Weight: 404 KB
Volume: 15
Category: Article
ISSN: 1472-7781
DOI: 10.1039/b000750l

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A synthesis of the km-trinlfornzyl rrrandrw moiety (3 J irl the marw nretubol~te hnlichondromide (I) is described. The synthesis feamres judiriolrs application of the Evarrs chirul uldol protocol in combinutio~~ with the controlled ring opening ofrhiml a-epoxy alcohol precursor molerules to elaborat