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Towards a Molecular Understanding of Asymmetric Heterogeneous Catalysis: Hydrogenation of 1-Phenyl-1,2-Propanedione1

✍ Scribed by E. Toukoniitty; P. Mäki-Arvela; V. Nieminen; T. Salmi; D. Yu. Murzin

Book ID
111548567
Publisher
Springer
Year
2003
Tongue
English
Weight
269 KB
Volume
44
Category
Article
ISSN
0023-1584

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Enantioselective hydrogenation of 1-phen
Enantioselective hydrogenation of 1-phenyl-1,2-propanedione, ethyl pyruvate and acetophenone on Ir/SiO2 catalysts: Effect of iridium loading
✍ Teresita Marzialetti; Marcelo Oportus; Doris Ruiz; José Luis García Fierro; Patr 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 942 KB

The effect of the metal particle size and the modifier concentration on the enantioselectivity (ee) and the conversion level in the hydrogenation of three different substrates: 1-phenyl-1,2-propanedione, ethyl pyruvate and acetophenone were studied over Ir/SiO 2 catalysts. The metal loading was vari