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Solvent effects in enantioselective hydrogenation of 1-phenyl-1,2-propanedione

✍ Scribed by E Toukoniitty; P Mäki-Arvela; J Kuusisto; V Nieminen; J Päivärinta; M Hotokka; T Salmi; D.Yu Murzin


Book ID
104422099
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
260 KB
Volume
192
Category
Article
ISSN
1381-1169

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Enantioselective hydrogenation of 1-phen
✍ Teresita Marzialetti; Marcelo Oportus; Doris Ruiz; José Luis García Fierro; Patr 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 942 KB

The effect of the metal particle size and the modifier concentration on the enantioselectivity (ee) and the conversion level in the hydrogenation of three different substrates: 1-phenyl-1,2-propanedione, ethyl pyruvate and acetophenone were studied over Ir/SiO 2 catalysts. The metal loading was vari