𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Toward the total synthesis of elisapterosin B: a Hg(OTf)2-promoted diastereoselective intramolecular Friedel–Crafts alkylation reaction

✍ Scribed by Weijiang Ying; Charles L. Barnes; Michael Harmata

Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
488 KB
Volume
52
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

As part of an approach to the synthesis of the antitubercular agent elisapterosin B, we prepared two different chiral, non-racemic olefinic substrates and examined their diastereoselective ring closure using mercury salts. The effort yielded potential precursors to elisapterosin B in good yield with good to excellent diastereocontrol.

📜 SIMILAR VOLUMES

Total Synthesis of (.+-.)-Taiwaniaquinol
Total Synthesis of (.+-.)-Taiwaniaquinol B via a Domino Intramolecular Friedel—Crafts Acylation/Carbonyl α-tert-Alkylation Reaction.
✍ Eric Fillion; Dan Fishlock 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 10 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access the actual ChemInform Abstract, please click on HTML or PDF.

Synthesis of Polycyclic and 4,5-Diacylth
Synthesis of Polycyclic and 4,5-Diacylthiophene-2-carboxylates via Intramolecular Friedel—Crafts Alkylations and Unusual Autooxidative Fragmentation of the Derivatives Obtained from the Samarium Diiodide-Promoted Coupling Reactions of Thiophene-2-carboxylate with Carbonyl Compounds.
✍ Shyh-Ming Yang; Jim-Min Fang 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.