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Toward the spectroscopic identification of vinylidene, H2CC

✍ Scribed by Yoshihiro Osamura; Henry F. Schaefer III

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
319 KB
Volume
79
Category
Article
ISSN
0009-2614

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✦ Synopsis

The smglet electromc ground state of vmyhdene WIU be very dtfficult to observe spectroscopically, as It rapldly tunnels througfi a small (6 kcal mol-'1 barner to acetylene TrIplet vmyhdene should have a much longer hfetune, and several prelctlons of Its PropertIes are reported here These mclude the mfrared spectrum and a characterlzatton of the allowed 3Bz -

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