𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Infrared spectra of matrix-isolated propadienethione, H2CCCS

✍ Scribed by Eiichi Suzuki; Fumio Watari

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
278 KB
Volume
168
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Pyrolysis (900 K) of cyclopenteno-1.2,3-thiadiazole with trapping of the products in argon at 20 K gave ethylene and propadienethione. Small quantities of thioketene and trimethylenethioketene were also formed. The infrared bands due to propadienethione were identified by their disappearance on irradiation.

📜 SIMILAR VOLUMES

High Resolution Infrared Study of the ν1
High Resolution Infrared Study of the ν11 Level in H2C[]13C[]CH2
✍ F. Hegelund; H. Burger; O. Polanz 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 524 KB

The lowest fundamental level \(v_{11}\) in \(2-{ }^{13} \mathrm{C}\) allene, \(\mathrm{H}_{2} \mathrm{C}=-{ }^{13} \mathrm{C}-\mathrm{CH}_{2}\), has been studied from a high resolution infrared spectrum of the \(v_{11}\) band together with lower state combination differences obtained from high resol

The High-Resolution Infrared Spectrum of
The High-Resolution Infrared Spectrum of the ν9, ν10 Band System in H2C13CCH2
✍ F. Hegelund; H. Burger; O. Polanz 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 640 KB

The infrared spectrum of the \(\nu_{9}\) and \(\nu_{10}\) bands in \(\mathrm{H}_{2} \mathrm{C}={ }^{13} \mathrm{C}=\mathrm{CH}_{2}\) has been studied at a resolution of 0.003 to \(0.004 \mathrm{~cm}^{-1}\). The bands interact globally by \(z\)-Coriolis resonance, and several additional vibrational a