✦ LIBER ✦

Toward the enantioselective total synthesis of lyngbyatoxin A: on the stereocontrolled introduction of the quaternary stereogenic centre

✍ Scribed by Janne E Tønder; David Tanner

Book ID: 104205473
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 352 KB
Volume: 59
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(03)00822-6

No coin nor oath required. For personal study only.

✦ Synopsis

This paper deals with an approach to the enantioselective total synthesis of Lyngbyatoxin A, with focus on the stereocontrolled introduction of the quaternary stereogenic centre. The key step in the synthesis involves an enantiospecific Lewis-acid mediated rearrangement of chiral vinyl epoxides carrying a 7-substituted indole moiety.

📜 SIMILAR VOLUMES

Toward the Enantioselective Total Synthe

Toward the Enantioselective Total Synthesis of Lyngbyatoxin A: On the Stereocontrolled Introduction of the Quaternary Stereogenic Center.

✍ Janne E. Toender; David Tanner 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 64 KB

Enantioselective TADMAP-Catalyzed Carbox

Enantioselective TADMAP-Catalyzed Carboxyl Migration Reactions for the Synthesis of Stereogenic Quaternary Carbon.

✍ Scott A. Shaw; Pedro Aleman; Justin Christy; Jeff W. Kampf; Porino Va; Edwin Ved 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 49 KB

Enantioselective TADMAP-Catalyzed Carbox

Enantioselective TADMAP-Catalyzed Carboxyl Migration Reactions for the Synthesis of Stereogenic Quaternary Carbon

✍ Shaw, Scott A.; Aleman, Pedro; Christy, Justin; Kampf, Jeff W.; Va, Porino; Vede 📂 Article 📅 2006 🏛 American Chemical Society 🌐 English ⚖ 324 KB

Enzymatic resolution of a quaternary ste

Enzymatic resolution of a quaternary stereogenic centre as the key step in the synthesis of (S)-(+)-citalopram

✍ Laura F. Solares; Rosario Brieva; Margarita Quirós; Isidro Llorente; Miguel Bayo 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 271 KB

Studies directed toward the total synthe

Studies directed toward the total synthesis of polycavernoside A. Enantioselective synthesis of the disaccharide component

✍ Jeffrey N. Johnston; Leo A. Paquette 📂 Article 📅 1995 🏛 Elsevier Science 🌐 French ⚖ 180 KB

Toward the Total Synthesis of the Brasil

Toward the Total Synthesis of the Brasilinolides: Stereocontrolled Assembly of a C1−C19 Polyol Segment

✍ Paterson, Ian; Mühlthau, Friedrich A.; Cordier, Christopher J.; Housden, Michae 📂 Article 📅 2009 🏛 American Chemical Society 🌐 English ⚖ 866 KB