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Toward the Enantioselective Total Synthesis of Lyngbyatoxin A: On the Stereocontrolled Introduction of the Quaternary Stereogenic Center.

✍ Scribed by Janne E. Toender; David Tanner

Book ID
101954391
Publisher
John Wiley and Sons
Year
2003
Weight
64 KB
Volume
34
Category
Article
ISSN
0931-7597

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Toward the enantioselective total synthe
Toward the enantioselective total synthesis of lyngbyatoxin A: on the stereocontrolled introduction of the quaternary stereogenic centre
✍ Janne E TΓΈnder; David Tanner πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 352 KB

This paper deals with an approach to the enantioselective total synthesis of Lyngbyatoxin A, with focus on the stereocontrolled introduction of the quaternary stereogenic centre. The key step in the synthesis involves an enantiospecific Lewis-acid mediated rearrangement of chiral vinyl epoxides carr