Totalsynthese, Konfiguration und biologische Evaluierung von Anguinomycin C
✍ Scribed by Simone Bonazzi; Stephan Güttinger; Ivo Zemp; Ulrike Kutay; Karl Gademann
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 597 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Summa~y. The diphenol 1 was resolved into its antipodes and tlicir absolute configuration was established. The lcvorotatory isomer R-( -)-1 was oxidized t o thc dienone I?-( -) -6 , which was rearrangcd t o afford natural (-)-niultifloraminc ( R -( -)-7), thus cstablishing that tlic latter has the R
dariiberhinaus, daD bithylenoxid auch starke Basen wie Li-Alkylesie werden zur Bildung der Phosphorane aus Phosphoniumsalzen verwendet [Slersetzen kann. ## Arbeitsvorschrift : Man last in 5 ml Methylenchlorid 6.6 g (CsH5)3P (0,025 mol), 2.6 g Benzaldehyd (0,025 mol), 2.5 ml khylenoxid (0.05 mol)