## Abstract For Abstract see ChemInform Abstract in Full Text.
Total synthesis of α-bisabolol-3-one and deodarone
✍ Scribed by Y. Gopichand; K.K. Chakravarti
- Book ID
- 104243147
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 128 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Support of the Japan Science and Technology Corporation (JST) is gratefully acknowledged.
## Abstract A simple, efficient, and stereospecific total synthesis of (±)‐3α, 18‐dihydroxy‐17‐noraphidicolan‐16‐one **(2)**, by solvolytic rearrangement of the __endo__‐bicyclo‐[2.2.2]oct‐5‐en‐2‐yl methanesulfonate **16**, is described. Since aphidicolin **(1)** has already been obtained from **2*
THE total synthesis of several steroids (1.2) has previously been reported from this laboratory. In this communication a straightforward total synthesis of rec. 5a-preQnan-3~-ol-20-one (XIIIa) is reported. '3 All melting points were measured on Kofler block and corrected. '