✍ Scribed by Schlessinger, R. H.; Li, Yu-Jang
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The synthesis of the C-19 through C-27 segment of the marine natural product okadaic acid was accomplished employing a highly enantio-and diasteroselective aldol coupling reaction of a chiral vinylogous urethane lactone enolate. The remainder of the carbon skeleton of this segment was constructed by
The synthesis of the C-28 through C-38 segment of the marine natural product okadaic acid was accomplished employing a highly enantio-and diasteroselective aldol condensation reaction of a chii vinylogous urethane enolate. The stereocenter at C-29 was addressed utilizing a diastereoselective hydrobo
Synthesis of the C 19 Through C 27 Segment of Okadaic Acid Using Vinylogous Urethane Aldol Chemistry. Part 3. -The approach towards the C 19 -C 27 fragment (X) of okadaic acid is accomplished employing a highly enantio-and diastereoselective aldol coupling reaction of the chiral vinylogous urethane