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Total Synthesis of the Unusual Monoterpenoid Indole Alkaloid (±)-Alstilobanine A

✍ Scribed by Feng, Yiqing; Majireck, Max M.; Weinreb, Steven M.


Book ID
118751904
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
360 KB
Volume
124
Category
Article
ISSN
0044-8249

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✍ Priv.-Doz. Dr. Dietrich Spitzner; Prof. Dr. Ernest Wenkert 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB 👁 2 views

The tetrahedrane framework with R=tBu and the octabisvalene framework with R = CH3 presumably form because of steric reasons. Whereas the hydrocarbon 2 is highly strained, the arrangement in 1 is largely strain-free, based on the intermolecular contact distances. With other residues R the occurrenc