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Total synthesis of the proposed structure for pochonicine and determination of its absolute configuration

✍ Scribed by Kitamura, Yujiro; Koshino, Hiroyuki; Nakamura, Takemichi; Tsuchida, Aya; Nitoda, Teruhiko; Kanzaki, Hiroshi; Matsuoka, Koji; Takahashi, Shunya

Book ID
123453587
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
794 KB
Volume
54
Category
Article
ISSN
0040-4039

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The first total synthesis of putaminoxin
The first total synthesis of putaminoxin and determination of its absolute configuration
✍ Gowravaram Sabitha; K. Yadagiri; R. Swapna; J.S. Yadav πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 238 KB

Asymmetric synthesis of putaminoxin, a phytotoxic macrolide from the cultured dinoflagellate Amphidinium sp., has been accomplished. Absolute configuration of putaminoxin was concluded to be 1 from comparison of the NMR data and [a] D values of synthetic and natural putaminoxin.