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Total synthesis of the aglycone of venturicidins A and B - II

✍ Scribed by Hiroyuki Akita; Harutami Yamada; Hiroko Matsukura; Tadashi Nakata; Takeshi Oishi


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
252 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis


The C15-C27 segment 2 of the aglycone ,$ of venturicidins A and B was synthesized and then total synthesis of 3 was accomplished via intramolecular Wittig-Horner reaction of the ester from 2 and the previously synthesized Cl-Cl4 segment 1. In the preceding paper, the synthesis of the Cl-Cl4 segment l_ corresponding to the bottom half of the aglycone 2 of venturicidins A and B1) was reported.


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