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Synthesis of the C15–C27 portion of venturicidins: a formal total synthesis of venturicidin X

✍ Scribed by Keiji Tsunashima; Mitsuaki Ide; Hiroshi Kadoi; Aya Hirayama; Masaya Nakata

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
84 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

The C15-C27 portion of venturicidin X was prepared using substitution reactions of alkyl trifluoromethanesulfonates with a vinylmetal compound followed by homogeneous hydrogenation. Together with our previous synthesis of the C1-C14 portion of venturicidin X, a formal total synthesis of venturicidin X was completed.

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