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TOTAL SYNTHESIS OF TETRACYCLINES. I. (±)-DEDIMETHYLAMINO-12a-DEOXY-6-DEMETHYLANHYDROCHLOROTETRACYCLINE

✍ Scribed by Boothe, James H.; Kende, Andrew S.; Fields, Thomas L.; Wilkinson, Raymond G.

Book ID
126125894
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
269 KB
Volume
81
Category
Article
ISSN
0002-7863

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✍ A.I Gurevich; M.G Karapetyan; M.N Kolosov; V.G Korobko; V.V Onoprienko; M.M Shem 📂 Article 📅 1964 🏛 Elsevier Science 🌐 French ⚖ 194 KB

TKE development of methods for the CG-hydrcxylation of +chloro-5a,6-anhydrotetracycline (I; X = NMe2, Y = Cl, 2 3 0.R) ' and the C,2a-hydroxylaticn of various 12a4eoxytetracyclines, in particular (I; X = Y = Z = H) 2, has placed the 5a,6-anhydrotetracyclines (I) in the position of key intermediates