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Synthesis of 12a-deoxy-5a,6-anhydrotetracycline. The first total synthesis of the naturally occuring tetracycline

✍ Scribed by A.I. Gurevich; M.G. Karapetyan; M.N. Kolosov; V.G. Korobko; V.V. Onoprienko; S.A. Popravko; M.M. Shemyakin

Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
200 KB
Volume
8
Category
Article
ISSN
0040-4039

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TKE development of methods for the CG-hydrcxylation of +chloro-5a,6-anhydrotetracycline (I; X = NMe2, Y = Cl, 2 3 0.R) ' and the C,2a-hydroxylaticn of various 12a4eoxytetracyclines, in particular (I; X = Y = Z = H) 2, has placed the 5a,6-anhydrotetracyclines (I) in the position of key intermediates