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Total synthesis of steroids. IX. Synthesis of 11-oxidized 19-norandrostanes

✍ Scribed by Daniewski, A. R.; Guzewska, M.; Kocor, M.


Book ID
127378522
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
472 KB
Volume
40
Category
Article
ISSN
0022-3263

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First total synthesis of 11-oxa steroids
✍ FrΓ©dΓ©ric Cachoux; Malika Ibrahim-Ouali; Maurice Santelli πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 95 KB

The first total synthesis of 11-oxa steroids was achieved via an intramolecular Diels-Alder cycloaddition of orthoquinodimethane as the key-step.