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Total Synthesis of Spirastrellolide A Methyl Ester—Part 2: Subunit Union and Completion of the Synthesis

✍ Scribed by Ian Paterson; Edward A. Anderson; Stephen M. Dalby; Jong Ho Lim; Julien Genovino; Philip Maltas; Christian Moessner

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
377 KB
Volume
47
Category
Article
ISSN
0044-8249

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The novel antimitotic agent spirastrellolide A (1), isolated from the Caribbean sponge Spirastrella coccinea, is endowed with potent and selective phosphatase inhibitory properties. [1] Although the relative stereochemistry of each individual domain embedded into the macrocyclic frame of this marine