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Total Synthesis of Sarcophytol A, an Anticarcinogenic Marine Cembranoid

✍ Scribed by Takayanagi, Hisao; Kitano, Yasunori; Morinaka, Yasuhiro

Book ID
124153440
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
909 KB
Volume
59
Category
Article
ISSN
0022-3263

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Synthesis and stereochemistry of sarcoph
Synthesis and stereochemistry of sarcophytol B: An anticancer cembranoid
✍ John E. McMurry; Joseph G. Rico; You-nan Shih πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 218 KB

A short (5 step), efficient synthesis of sarcophytol B (1) from farnesal is reported using a low-temperature, titanium-induced pinacol coupling reaction of 1 ,lCdialdehyde 5 as the key step. An X-ray structure determination showed that sarcophytol B has trans diol stereochemistry.