N-Benzyl-2-deoxyxylonolactams are accessible by highly chemoselective, diastereoselective, and enantioselective carbon-hydrogen insertion reactions of diazoacetamides. Competing aromatic cycloaddition or b-lactam formation via carbon-hydrogen insertion into a benzylic position can be minimized by th
✦ LIBER ✦
Total Synthesis of (S)-(+)-Imperanene. Effective Use of Regio- and Enantioselective Intramolecular Carbon—Hydrogen Insertion Reactions Catalyzed by Chiral Dirhodium(II) Carboxamidates.
✍ Scribed by Michael P. Doyle; Wenhao Hu; Marcela V. Valenzuela
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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