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Enantioselective Synthesis of 3-Arylindan-1-ones via Intramolecular C—H Insertion Reactions of α-Diazo-β-ketoesters Catalyzed by Chiral Dirhodium(II) Carboxylates.

✍ Scribed by Yoshihiro Natori; Masahiro Anada; Seiichi Nakamura; Hisanori Nambu; Shunichi Hashimoto

Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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ChemInform Abstract: Highly Enantioselec
ChemInform Abstract: Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C—H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates.
✍ M. ANADA; N. WATANABE; S. HASHIMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 2 views

Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy