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Total synthesis of proposed structure of xylogiblactone B by chiron approach

✍ Scribed by Krishna, Palakodety Radha; Kunde, Ramesh; Nomula, Rajesh; Ramakrishna, Kallaganti V.S.


Book ID
125811429
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
303 KB
Volume
55
Category
Article
ISSN
0040-4039

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## Abstract The stereocontrolled synthesis of goniothalesdiol A, a dihydroxylated tetrahydropyran compound, has been accomplished using D‐ribose as chiral precursor. The key steps involved are aryl __Grignard__ reaction, stereoselective alkoxy‐directed keto reduction, and intramolecular oxy‐__Micha