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Total synthesis of (.+-.)-pentalenolactone E methyl ester

✍ Scribed by Paquette, Leo A.; Schostarez, Heinrich; Annis, Gary D.

Book ID: 126162950
Publisher: American Chemical Society
Year: 1981
Tongue: English
Weight: 279 KB
Volume: 103
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00411a056

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The naturally occurruq enantlomer of peatalenolactone E was synthesized as Its levorotatory Me ester 1 starting from (+)-2-ethoxycarbonyl-7,7-ethylenedioxyblcyclo[3.3.0loctan-3-one 3, which was obtarrxl by treatng (?)-3 with baker's yeast. The absolute configuration of pentalenolactone E Me ester wa