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Stereocontrolled total synthesis of (.+-.)-pentalenolactone P methyl ester

โœ Scribed by Kang, Ho Jung; Ra, Choon Sup; Paquette, Leo A.


Book ID
126323355
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
267 KB
Volume
113
Category
Article
ISSN
0002-7863

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SYnthesis and absolute configuration of
โœ Kenji Mori; Masahiro Tsuji ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 737 KB

The naturally occurruq enantlomer of peatalenolactone E was synthesized as Its levorotatory Me ester 1 starting from (+)-2-ethoxycarbonyl-7,7-ethylenedioxyblcyclo[3.3.0loctan-3-one 3, which was obtarrxl by treatng (?)-3 with baker's yeast. The absolute configuration of pentalenolactone E Me ester wa