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Total synthesis of muconin

โœ Scribed by Shunya Takahashi; Akemi Kubota; Tadashi Nakata

Book ID
104252349
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
98 KB
Volume
43
Category
Article
ISSN
0040-4039

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A convergent total synthesis of the tetrahydropyran-bearing acetogenin (ฯฉ)-muconin 1 is described. All five chiral building blocks 7, 9, 17, 21, and 29 were prepared from d-glutamic acid, respectively. Four out of them were used to furnish the alkyne 16 and the iodoalkyne 33, respectively, and palla