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Total synthesis of monoterpenoid isoquinoline alkaloids

✍ Scribed by Richard T. Brown; Martin F. Jones

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
180 KB
Volume
25
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

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Regioselectivity in isoquinoline alkaloid synthesis is analyzed here. Our experiments have shown that substituents on the aromatic ring of the starting amine are determinant in isoquinoline synthesis. The use of dicyclohexylcarbodiimide in activating carboxylic acids for electrophilic aromatic subst

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## Abstract The studied tetrahydroisoquinolines 1, 2 and 3 were synthesized from a common intermediate 6, which was prepared by addition of the lithium salt of dithiane 5 to hydrastinine chloride (4).