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Total synthesis of (±)-methyl 3-(3-isocyano-6-oxabicyclo[3.1.0]hex-2-en-5-yl)-2-propenoate

✍ Scribed by Tohru Fukuyama; Yat Ming Yung

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
109 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

The total synthesis of (*)-methyl 3-(3-isocyano-6-oxabicyclo[3.l.O]hex-2-en-5-y1)-2-propenoate has been achieved using 3-tosyl-2-azabicyclo[2.2.l]hepta-2,5-diene as a key starting material.

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✍ Dyakonenko, Viktoria V. ;Shishkin, Oleg V. ;Zbruev, Alexandr V. ;Desenko, Sergey 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 130 KB

In the crystal structure of the title compound, C 18 H 17 N 3 O 2 , the imidazoline ring has a very flattened envelope conformation, with a twisted endocyclic C N double bond.