Total synthesis of (+)-ligudentatol via Photoaddition-Fragmentation-Aromatic Annulation sequence

✍ Scribed by Nizar Haddad; Husein Salman

• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 186 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)21374-2

✦ Synopsis

First synthesis of the naturally occurring compound (+)-ligudentatol is presented. It demonstrates the synthetic utility of the "Photoaddition-Fragmentation-Aromatic Annulation" sequence, recently developed v/a the intramolecular photocycloaddition of dihydropyrones to I alkenes.