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Synthesis of substituted phenols Via photoaddition-fragmentation-aromatic annelation sequence

✍ Scribed by Nizar Haddad; Irina Kuzmenkov


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
189 KB
Volume
37
Category
Article
ISSN
0040-4039

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Total synthesis of (+)-ligudentatol via
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First synthesis of the naturally occurring compound (+)-ligudentatol is presented. It demonstrates the synthetic utility of the "Photoaddition-Fragmentation-Aromatic Annulation" sequence, recently developed v/a the intramolecular photocycloaddition of dihydropyrones to I alkenes.