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Total Synthesis of Indole Alkaloid (±)-Subincanadine E

✍ Scribed by Tian, Jingjing; Du, Qiuchen; Guo, Rui; Li, Yun; Cheng, Bin; Zhai, Hongbin

Book ID
121870425
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
677 KB
Volume
16
Category
Article
ISSN
1523-7060

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The tetrahedrane framework with R=tBu and the octabisvalene framework with R = CH3 presumably form because of steric reasons. Whereas the hydrocarbon 2 is highly strained, the arrangement in 1 is largely strain-free, based on the intermolecular contact distances. With other residues R the occurrenc