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Total Synthesis of (+)-Hygrine via Asymmetric Phase-Transfer Catalytic Alkylation

โœ Scribed by Lee, Jeong-Hee; Jeong, Byeong-Seon; Ku, Jin-Mo; Jew, Sang-sup; Park, Hyeung-geun


Book ID
120920861
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
122 KB
Volume
71
Category
Article
ISSN
0022-3263

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Catalytic enantioselective synthesis of
โœ Graham B. Jones; Robert S. Huber; Brant J. Chapman ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 874 KB

Catalytic enantioselective syntheses of the macrolides (R)-(-) phoracantholide and (R)-(+) lasiodiplodin have been achieved. Stereochemistry was introduced in using an arene chromium tricarbonyl derived catalyst, which mediated the enantioselective addition of dimethyl zinc to a functionalized aldeh