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Total synthesis of humulene

✍ Scribed by Corey, Elias J.; Hamanaka, Ernest.


Book ID
120218146
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
289 KB
Volume
89
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


A biomimetic chemical synthesis of humul
✍ E.J. Corey; Sylvain Daigneault; Brian R. Dixon πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 259 KB

## The first synthesis of humulene (1) by a biomimetic cation-olefin cyclization route is reported. Although several syntheses of the structurally interesting cyclic ttiene humulene (1) have been devel-1 the direct formation of this sesquiqne iiom its biogenetic pmcmsor E&famesol has never been mp

Structure of humulene
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Stereospecific synthesis of humulene by
✍ John E. McMurry; James R. Matz πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 104 KB

An efficient stereospecific synthesis of humulene was accomplished using tdaniuminduced cyclization of 3,3,7-trimethyl-ll-oxoundeca-4E,7E-dienal as the key step.

Humulene triepoxide
✍ Murray-Rust, P. ;Murray-Rust, J. πŸ“‚ Article πŸ“… 1977 πŸ› International Union of Crystallography βš– 229 KB