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Total Synthesis of Fully Acetylated N -Acetylneuraminic Acid (Neu5Ac), 2-Deoxy-β-Neu5Ac, and 4- epi -2-Deoxy-β-Neu5Ac from d -glucose

✍ Scribed by Li, Lian-Sheng; Wu, Yu-Lin; Wu, Yikang


Book ID
127273296
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
135 KB
Volume
2
Category
Article
ISSN
1523-7060

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The reaction of the peracetate methyl es
✍ Gaik B. Kok; Brendan L. Mackey; Mark von Itzstein 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 445 KB

The reaction of the peracetate methyl esters of N-acetylneuraminic acid (Neu5Ac), 3-deoxyq~glycero-D-galacto-2-nonulosonic acid (Kdn), and 3-deoxy-D-manno-2-octulosonic acid (Kdo) with trimethylsilyl trifluoromethanesulfonate (CF3SO3SiMe 3) has been reinvestigated. We have found that the choice of s