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Total synthesis of (+)-epiquinamide from d-mannitol

โœ Scribed by Subhash Ghosh; J. Shashidhar

Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
154 KB
Volume
50
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The total synthesis of (+)-epiquinamide, a novel quinolizidine alkaloid isolated from the Ecuadoran poison frog, Epipedobates tricolor is described. The key step includes a ring-closing metathesis reaction to construct both the six member rings. D-Mannitol was used as a chiral pool material.

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