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Total Synthesis of (-)-Dihydrocorynantheol (IV) Using Bicyclo[3.2.1]octenone Chiral Building Block (I).

โœ Scribed by Ayako Tosaka; Shinichiro Ito; Norio Miyazawa; Masatoshi Shibuya; Kunio Ogasawara; Yoshiharu Iwabuchi


Publisher
John Wiley and Sons
Year
2007
Weight
19 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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An efficient synthesis of optically acti
โœ Yongcheng Song; Sentaro Okamoto; Fumie Sato ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 137 KB

An efficient synthesis of optically active (2R,3R)-2-methyl-3-[(1R)-1-methylprop-2-enyl]cyclopentanone, a useful chiral building block for synthesis of vitamin D and steroids, has been developed starting from readily accessible optically active secondary propargyl phosphate (R)-2, where the asymmetr