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Total Synthesis of (+)-Curacin A, a Novel Antimitotic Metabolite from a Cyanobacterium.

โœ Scribed by James C. Muir; Gerald Pattenden; Tao Ye

Publisher
John Wiley and Sons
Year
2003
Weight
89 KB
Volume
34
Category
Article
ISSN
0931-7597

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The title compound (XV) is synthesized via highly stereoselective allylation of the aldehyde (VIII), Wittig reaction of the phosphonium salt (XI) with the aldehyde (XII), and condensation of the amino thiol (XIII) with the acid (XIV). -(ONODA, T.;