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Total Synthesis of Cruentaren A

✍ Scribed by Viktor V. Vintonyak; Martin E. Maier

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
113 KB
Volume
119
Category
Article
ISSN
0044-8249

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Total Synthesis of Cruentaren A
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## Abstract An expeditious total synthesis of the highly cytotoxic F‐ATPase inhibitor cruentaren A (**1**) is described based on a ring‐closing alkyne metathesis (RCAM) reaction for the formation of the macrocylic ring. Other key transformations comprise a C‐acylation of the benzyl lithium reagent