Total synthesis of chiro-inositol 2,3,5-trisphosphate: A myo-inositol 1,4,5-trisphosphate analogue from benzene via photo-oxidation
โ Scribed by Howard A.J. Carless; Kofi Busia
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 231 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
t\_-Quebrachitol was O-demethylated to give lt\_-chiro-inositol which, on treatment with dibutyltin oxide, benzyl chloride, and tetrabutylammonium iodide in acetonitrile, gave mainly crystalline lo-2,3,5tri-0-benzyl-chiro-inositol (Sal together with lt\_-2,3,5,6-tetra-0-benzyl-chiro-inositol. Catal
Partial benzoylation of the 3,4-dibenzyl ethers of D- and L-chiro-inositol provided the 1,2,5-tri-O-benzoyl-3,4-di-O-benzyl-chiro-inositols. Inversion of the free axial hydroxyl group gave a mixture of chiral 1,3,4- and 1,2,4-tri-O-benzoyl-5,6-di-O-benzyl-myo-inositols [W. Tegge and C. E. Ballou, Pr