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Total Synthesis of (+)-Brasilenyne. Application of an Intramolecular Silicon-Assisted Cross-Coupling Reaction.

✍ Scribed by Scott E. Denmark; Shyh-Ming Yang

Publisher: John Wiley and Sons
Year: 2005
Weight: 9 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200508234

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The investigation of a silicon-mediated coupling reaction between hydroxyl and carbonylimidazolide functional groups in the preparation of carbonate linkages is described. Application of this reaction to the formation of aliphatic polycarbonates was accomplished by the polymerization of an AB monome