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Total Synthesis of (.+-.)-Aspidofractinine and (.+-.)-Aspidospermidine

โœ Scribed by Wenkert, Ernest; Liu, Song


Book ID
125972862
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
791 KB
Volume
59
Category
Article
ISSN
0022-3263

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The pentacyclic skeleton 10 of the aspidospermine group of indole alkaloids has been constructed from hexahydrocarbazol-4-one 2 with high stereoselectivity. The synthesis of(k) 19-0~0 aspidofractinine 12, a direct precursor of aspidofractinine 4, illustrates the usefulness of this new general strat

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