Total Synthesis of (−)- and ent -(+)-Vindoline and Related Alkaloids
✍ Scribed by Ishikawa, Hayato; Elliott, Gregory I.; Velcicky, Juraj; Choi, Younggi; Boger, Dale L.
- Book ID
- 120267258
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 591 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The general reactivity of various sites in the vindoline series has been investigated. The facility of electrophilic substitution at C(15) and the effect of steric crowding on reactions at C(4) are discussed. At the basic nitrogen sites, oxidations with mercuric acetate and potassium pe