Total synthesis of (+)-anamarine
โ Scribed by Kumar, Krishnammagari Suresh; Reddy, Cirandur Suresh
- Book ID
- 120643714
- Publisher
- Royal Society of Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 197 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1477-0520
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The di-acetonide of 6-deoxy-aLdehydo-D-qlucose Lz and (S,S)-2-ethoxy-6-triphenylphosphoniomethyl-dihydropyran iodide 2 are elaborated from D-glucose each in practicable procedures of 5 and 10 steps, resp., and subsequently joined to give, after oxidation, deprotection and acetylation, (-I-anamarine
The (R R)-6-alkoxy-2-triphenylphosphoniomethyl-dihydropyran iodide 2 and the --di-acetonide of 6-deoxy-aldehydo-L-glucose 3 are elaborated from (R,R)-tartrate and D-gulonolactone, resp., and subsequently joined to yield (+)-anamarine (l), identical with the Hyptis-derived product.