An efficient total synthesis of (−)-anamarine
✍ Scribed by Palakuri Ramesh; H.M. Meshram
- Book ID
- 113930922
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- French
- Weight
- 542 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The di-acetonide of 6-deoxy-aLdehydo-D-qlucose Lz and (S,S)-2-ethoxy-6-triphenylphosphoniomethyl-dihydropyran iodide 2 are elaborated from D-glucose each in practicable procedures of 5 and 10 steps, resp., and subsequently joined to give, after oxidation, deprotection and acetylation, (-I-anamarine
## A total synthesis of (+)-isokhusimone 2 has been accomplished efficiently involving the rearrangement of the mesylate 17 as a key step. Ar 1-5 cyclisation of the bromophenol 12 furnished the tricyclic clienone 13 which was subsequently converted into 17.