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Total synthesis of amorfrutin A via a palladium-catalyzed migratory prenylation–aromatization sequence

✍ Scribed by Sylvain Laclef; Katie Anderson; Andrew J.P. White; Anthony G.M. Barrett

Book ID
113930259
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
368 KB
Volume
53
Category
Article
ISSN
0040-4039

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A novel approach towards the synthesis of functionalized benzo[a]heptalenes 9 and 10 via a 6pelectrocyclic ring closure ± aromatization sequence of corresponding bis[prop-2-enoates] 5 and 6 has been developed (Scheme 1). The starting bis[prop-2-enoates] have been prepared from the corresponding dial