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Total synthesis of 11.beta.-methyl-19-norsteroids

โœ Scribed by Garland, R. B.; Palmer, J. R.; Pappo, R.


Book ID
124073779
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
734 KB
Volume
41
Category
Article
ISSN
0022-3263

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## Abstract The cationic cyclization of 2โ€[6โ€(__m__โ€methoxyphenyl)โ€(__E__)โ€3โ€hexenyl]โ€3,5โ€dimethylโ€2โ€cyclopentenol (**3**) was investigated. Exclusive formation of 1โ€ and 3โ€methoxyโ€15ฮฑ,17โ€dimethylโ€1,3,5(10), 13(17)โ€gonatetraene (**4** and **5**) was observed, indicating complete stereoselectivity i