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Total Synthesis of 10-Isocyano-4-cadinene and Determination of Its Absolute Configuration

✍ Scribed by Nishikawa, Keisuke; Nakahara, Hiroshi; Shirokura, Yousuke; Nogata, Yasuyuki; Yoshimura, Erina; Umezawa, Taiki; Okino, Tatsufumi; Matsuda, Fuyuhiko


Book ID
124101487
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
472 KB
Volume
12
Category
Article
ISSN
1523-7060

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The first total synthesis of putaminoxin
✍ Gowravaram Sabitha; K. Yadagiri; R. Swapna; J.S. Yadav πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 238 KB

Asymmetric synthesis of putaminoxin, a phytotoxic macrolide from the cultured dinoflagellate Amphidinium sp., has been accomplished. Absolute configuration of putaminoxin was concluded to be 1 from comparison of the NMR data and [a] D values of synthetic and natural putaminoxin.